Longshadow wrote:
You can, you need to use a different compound.
Yes, the OP may have, but tarnish and rust are both oxidations of a metal, different references to different metals, different types of oxide compounds.
Saying "Silver does not rust." is a misnomer. While it doesn't produce the same physical characteristics of the base element oxide, rust is oxidation, just like tarnish is oxidation. Both metals oxidize.
Rust is not necessarily restricted to iron, and tarnish is not restricted to silver or brass.
However they are most commonly used that way.
Iron oxide is can be ugly, lumpy, and flaky, while tarnish looks like a coating. But I've seen iron look like it has a smooth brown coating.
And we can discuss semantics well into the evening.........
You can, you need to use a different compound. br ... (
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There is a definite difference between “rusting” and “corrosion”.
Almost all metals will react with oxygen or other elements to change shape or finish; this is corrosion.
Metals or alloys containing iron combine as FeO, Fe2O3, or Fe3O4: this is rusting.
[Common practice (in chemistry, engineering, alloying and similar aspects of “the trade”), regard “RUST” as being exclusively restricted to Iron and its oxides]. There may be an alteration of a metals surface finish, AKA tarnishing.A list of non-reactive metals:
“. . . the Noble Metals are metals that are resistant to Corrosion and Oxidation in moist air (unlike most Base Metals). The short list of chemically noble metals (those elements upon which almost all chemists agree) comprises Ruthenium (Ru), Rhodium (Rh), Palladium (Pd), Silver (Ag), Osmium (Os), Iridium (Ir), Platinum (Pt), and Gold (Au).
More inclusive lists include one or more of Mercury (Hg), Rhenium (Re) and Copper (Cu) as noble metals. On the other hand, Titanium (Ti), Niobium (Nb), and Tantalum (Ta) are not included as noble metals although they are very resistant to corrosion.” —Quora answer by Mr. Roy.
As far as pure (or slightly alloyed metals) go, Tungsten, Nickel, Titanium, Zirconium and Aluminum would be added. Aluminum, Titanium, zirconium (and some others) are interesting because of the oxide-layer (Al2O3, in the case of Aluminum) formed, this is the same as corundum i.e. ruby, sapphire; hard, tough, nonreactive.
Iron and steel alloys with sufficient quantities (%) of Chromium (10 to 30%) are rust resistant.
Silver does oxidize, at least on the surface. Large quantities of silver coins have been retrieved that have had enough of the parent metal oxidized that it has become one large black lump. The same with metallic copper.
An example of the current properties of the elements of group 10 are at:
https://en.m.wikipedia.org/wiki/Group_10_element.
Data for group 11 are at:
https://en.m.wikipedia.org/wiki/Group_11_elementA similar analysis is available for other groups.
[NOTE: the latest IUPAC nomenclature has done away with the older group 8A or group 8B titling, making the look-up of information a bit confusing.]
In an historical perspective [geologically], prior to a lot of life-on-earth, the environment was Reducing, i.e. without oxygen. Rainfall, runoff, and erosion had transported very large quantities of iron and other metal —in reduced form— into the worlds oceans, which were essentially an iron and sulfur (and other elements) rich “soup”.
When algae, bryozoans, and other oxygen-producing lifeforms began producing Oxygen as a waste-product from photosynthesis, the oxygen content increased to levels that caused a reaction with iron and precipitated vast quantities of iron in
Banded Iron Formations, that are found worldwide.
In essence, “the world rusted”.