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Hydrogen vehicles
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Dec 30, 2020 14:52:24   #
Meadwilliam
 
Fuel cell or internal combustion engine...oxidation is still oxidation.

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Dec 30, 2020 14:56:14   #
petrochemist Loc: UK
 
Meadwilliam wrote:
Fuel cell or internal combustion engine...oxidation is still oxidation.


That is true but the fuel cell is typically substantially more efficient. I'm sure it's not just due to lacking the sound (which tends to be better from internal combustion).

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Dec 30, 2020 14:58:31   #
DirtFarmer Loc: Escaped from the NYC area, back to MA
 
Meadwilliam wrote:
Fuel cell or internal combustion engine...oxidation is still oxidation.

petrochemist wrote:
That is true but the fuel cell is typically substantially more efficient.

Also, using air in an internal combustion engine can produce oxides of nitrogen, contributing to smog.

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Dec 30, 2020 17:37:39   #
John Hicks Loc: Sible Hedinham North Essex England
 
How big would the batteries have to be to power a large bulldozer, I cannot any batteries lasting more the two hours on a bull dozer.
The only way to have an electric bull dozed would be to ha six foot diameter wheel on it to which an electric cable would be run so that when The dozed goes forward it lets out cable and when it reverses it winds it in again with one end attached to the dozed and one end to a three phase power supply

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Dec 30, 2020 17:45:12   #
David in Dallas Loc: Dallas, Texas, USA
 
My biggest concern would be safety. For efficient storage, hydrogen must be contained at very high pressure. Not only that, it is the smallest of all molecules and very difficult to distribute without leaks. And worst of all, it burns with an invisible flame--something could be on fire and not noticed. I wouldn't drive a hydrogen-powered automobile.

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Dec 30, 2020 17:45:51   #
DirtFarmer Loc: Escaped from the NYC area, back to MA
 
I would think the power requirements of a bulldozer would be similar to a large truck. The truck has to use the power for overcoming air resistance when travelling at high speed. The bulldozer needs the power to overcome the resistance of what it's pushing around at slow speed. It's geared way down. I've never seen a racing bulldozer.

So if we can make electric trucks, it should be possible to make electric bulldozers.
And the size of the batteries isn't that important. Bulldozers need weight for traction and a large battery would probably contribute to that.

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Dec 30, 2020 17:53:15   #
John Hicks Loc: Sible Hedinham North Essex England
 
You are missing the point the reactive effort of a large bull dozed needs to be far higher than a large truck, the resistance to movement of tyred wheels on a road is negligible compared to the reactive effort required for a bull dozed to move a large quantity of soil or other matter.
The bill dozed would have to have a gear box so the the electric motor could turn at speed that the gearbox would transform mechanically to it tracks and batteries would never be able to provide the continuous power needs all day long for the dozed to work. This is why the dozed would need to be connected to a three phase mains supply

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Dec 30, 2020 18:29:34   #
DirtFarmer Loc: Escaped from the NYC area, back to MA
 
Trucks need a lot of power to get up hills so I expect they would need a large engine. Trucks move a lot of weight and that takes power when it’s uphill.The engine speed is not really important because it is geared down in both vehicles. Geared down more for dozers.

And the tire resistance is small compared to the air resistance of a large truck at highway speeds.

Actually I suspect that the large dozers use hydraulic drive systems rather than gear boxes.

Again, I believe that if it can be done for a truck then it could be done for a dozer. In my limited experience with bulldozers they get used in spurts, moving a pile, then going back for another. Trucks run continuously for long times.

I must admit that I have no expertise in battery vehicle design.

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Dec 30, 2020 18:48:47   #
macatac
 
Bison Bud wrote:
Something somewhat new is the production of "Green Hydrogen" by using solar, wind, or hydro sources of electricity to power the electrolysis process to produce the hydrogen. However, I think the real problem with hydrogen as a viable fuel is primarily how to safely store and transport it. I sure don't want any 10,000 PSI bottles riding along with me in any vehicle or even traveling down the highway for that matter! Anyway, using "Green Hydrogen" as a back up storage medium to batteries seems to make good sense and may just catch on. Batteries have a finite capacity which production could exceed at times. Charge the batteries first, then as they become charged move the energy produced to the electrolysis process and store the hydrogen on site.
Something somewhat new is the production of "... (show quote)


Back in the 1960s there was a guy in Utah that started a company to manufacture buses and trucks that used
hydrogen as a fuel source. He had found a way to safely store hydrogen in tanks using anhydrous crystals.
To provide proof of the safety he set up a demonstration of three tanks of natural gas and one of hydrogen and one of hydrogen with anhydrous crystals. The three tanks where placed in a field and each was shot with a high powered rifle. The natural gas a hydrogen both exploded when hit, however the one with the crystals the bullet went through it with no explosion and a second shot ignited the escaping hydrogen but still no explosion.
At the time there was a Canadian company that was doing research on a high efficient electrolysis units to produce hydrogen, the thought was to use focused solar mirror arrays to produce high pressure steam that would drive turbines for the electricity for the electrolysis.
The USPS became interested and wanted to place an order for trial postal deliverer trucks, but there was never an order placed due to pressure from oil company executives. I remember seeing this on a Merve Griffen TV show where Griffen interviewed this guy and he went on to explain how he and his family were being threatened
and one of his plants had been fire bombed. He just gave it all up. While on this show he started to name some of the oil company executives but the tv network cut the whole live program off. I never ever heard anything more about this.

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Dec 30, 2020 19:22:53   #
Bison Bud
 
macatac wrote:
Back in the 1960s there was a guy in Utah that started a company to manufacture buses and trucks that used
hydrogen as a fuel source. He had found a way to safely store hydrogen in tanks using anhydrous crystals.
To provide proof of the safety he set up a demonstration of three tanks of natural gas and one of hydrogen and one of hydrogen with anhydrous crystals. The three tanks where placed in a field and each was shot with a high powered rifle. The natural gas a hydrogen both exploded when hit, however the one with the crystals the bullet went through it with no explosion and a second shot ignited the escaping hydrogen but still no explosion.
At the time there was a Canadian company that was doing research on a high efficient electrolysis units to produce hydrogen, the thought was to use focused solar mirror arrays to produce high pressure steam that would drive turbines for the electricity for the electrolysis.
The USPS became interested and wanted to place an order for trial postal deliverer trucks, but there was never an order placed due to pressure from oil company executives. I remember seeing this on a Merve Griffen TV show where Griffen interviewed this guy and he went on to explain how he and his family were being threatened
and one of his plants had been fire bombed. He just gave it all up. While on this show he started to name some of the oil company executives but the tv network cut the whole live program off. I never ever heard anything more about this.
Back in the 1960s there was a guy in Utah that sta... (show quote)


Wow, hydrogen stored in solid form as crystals sounds like a dream come true! If this technology indeed exists, then hydrogen as a viable fuel has some real hope. I will be looking into this further, thanks for the info.

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Dec 30, 2020 20:03:23   #
Daryls Loc: Waco, TX
 
dpullum wrote:
Alternate fuel is a new idea to the USA and when it reared its ugly non-greasy head the petro people have crushed it. Politicians are Oliogenous, indeed their palms are greased with the green. The subject of this post, Hydrogen is a very clean fuel, especially when generated using electricity from renewable sources.

When I was living in Argentina, Cabs were fueled with liquified natural gas or propane.

In the 1960s safe Thorium Nuclear Reactors designed for the airforce while not a good fit, these reactors were run for 5 years successfully. They ran with molten salt fuel which was self-regulating and if they were to overheat the fuel is dumped into a cool vessel to solidified. Solidified the nuclear reactivity stops. They burned waste from other reactors, run at high temperatures, and are not explosive water-cooled pressure cookers; ever heard of Chernobyl, Three Mile Island, and Fukushima?

The main drawback, no bomb material, and not profitable to Nixon's California friends. Nixon ordered all research to stop and all materials to be destroyed. Oops, the researchers took data home and a reactor was hidden in a museum. The USA is slow in allowing Molton Salt Thorium Reactors, other countries are building them as part of their renewable future, China, India, and others. Designs allow mass production of modular small reactors. Interesting subject ... do a Google/YouTube search and get educated in 5 minutes. Google Thorium Reactors in five minutes.

Elon Musk has started a revolution with E-Cars, more efficient Solar Cells, and storage of off-hour power with highly efficient battery systems.
Alternate fuel is a new idea to the USA and when i... (show quote)



Just like with these electric cars, folks are ignoring the inherent 'new' dangers associated with these alternate designs. For the thorium reactors, they produce uranium-232, which decays to an extremely potent high-energy gamma emitter that can penetrate through one meter of concrete. It will certainly travel through your home and car to you! Handling the spent nuclear fuel is also extraordinarily dangerous. Think of a car accident or an accident in your home with one of these reactors.

Many of the thorium advocates say that these thorium reactors produce little radioactive waste. While that may be true in the classic sense, they do produce a different spectrum of waste compared to those produced from uranium-235. Think of the many dangerous alpha and beta emitters, and isotopes with extremely long half-lives, including iodine-129 (half-life of 15.7 million years). These will impact life all around just from normal wear-and-tear with average consumer use.

These types of reactors MAY be a little less dangerous than regular uranium reactors (think weapons-grade nuclear materials, alpha, beta, gamma, neutron, heavy metal poisoning, etc.), but the hazards are still very dangerous, just different dangers and degrees of danger.

Back to those electric cars, first responders get killed responding to vehicular accidents way too often because of the electrical technology and chemicals incorporated in them. So, consider the different dangers when looking at alternatives and not just the potential benefits assumed, IF everything goes right all the time and Murphy stays in his cave. We will all live longer.

Daryl

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Dec 30, 2020 20:13:10   #
Daryls Loc: Waco, TX
 
aphelps wrote:
The electric calculation ignores the costs of building, operating and maintaining the much larger infrastructure needed to support the electric needs of large scale use of electric vehicles. The present grid would have to be really scaled up.


And it would NEVER work in California. They cannot even manage their electrical grid as it is now without all those electric cars/trucks/etc. Just imagine how bad the rolling brownouts/blackouts would be with more electric vehicles. The same would apply in most, if not all, the USA. And how would we power the generators to produce electricity - windfarms and solar panels? With current technology and distribution systems, I doubt that is feasible.

Daryl

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Dec 30, 2020 20:33:45   #
David in Dallas Loc: Dallas, Texas, USA
 
I don't think anyone is seriously recommending use of thorium reactors to power cars or homes--I think they'd be part of the electrical grid. They do have the societal advantage of not producing plutonium as a byproduct, so are not a source of bomb material.

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Dec 30, 2020 20:51:37   #
Daryls Loc: Waco, TX
 
I sure hope you are right David. That would be disasterous for the world if they used them domestically. Maybe in 100 years or more, but certainly not currently or in the near future.

Daryl

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Dec 30, 2020 22:24:30   #
David in Dallas Loc: Dallas, Texas, USA
 
Bison Bud wrote:
Wow, hydrogen stored in solid form as crystals sounds like a dream come true! If this technology indeed exists, then hydrogen as a viable fuel has some real hope. I will be looking into this further, thanks for the info.
I think this is a discussion of clathrates. Those are crystal-like structures that can entrap gas molecules. It is a technology that needs further investigation.

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