Flourescent lighting has been a problem for many photographers over the years. I wanted to start a discussion on the subject with some observations. Feel free to talk about your problems with fluorescent lighting (not including spelling) and your solutions.
Black body light sourcesThe sun, which produces our daylight, is roughly a black body source. That just means it looks like a body at a certain temperature. The apparent temperature of the sun is around 5500 degrees Kelvin. You all know that if you heat something up enough it will glow red. If you heat it up more it will get orange, then yellow. Red heat is around 900 degrees Kelvin. Yellow is around 3000 degrees Kelvin. The sun is very hot. At low temperatures, a body will emit light, but mostly in the infrared. When it starts to glow red, that’s the first indication of visible light. Light from the sun peaks in the green, which is very hot (near 9000 degrees Fahrenheit for you guys that don’t think in Celcius). The solar spectrum is not purely a black body curve since there are elements in the sun’s atmosphere that absorb light at certain wavelengths. That modifies the spectrum but in a broad sense it looks pretty much like a black body and it takes a spectrometer with good resolution to see the absorption lines, known as Fraunhofer lines, after the guy that discovered them. In the chart below the colors represent the visible part of the spectrum (horizontal axis) and everything to the right is infrared.
Source: Wikipedia article, image By Darth Kule - Own work, Public Domain, commons.wikimedia.org/w/index.php?curid=10555337
An incandescent light source (regular light bulb) has a spectrum similar to the 3000 degree Kelvin curve above. If you look at the 3000K line and the 5000K line in the above chart you can see that although the 5000K curve has about 8 units at the blue side of the curve and 11 units at the red side, the 3000K line has about 1 unit at the red side and very close to zero at the blue side. That’s why there’s a difference between the white balance for daylight and incandescent lighting. The light bulb will look redder because there’s more energy at the red side of the spectrum (relative to the total energy).
Fluorescent lightsFluorescent lamps generate light by a two-step process. The lamps have changed in recent years but the basic process is similar. A fluorescent bulb is a glass tube with a gas in it at low pressure, and a phosphor is coated onto the inside of the tube. A high voltage is applied to the ends of the tube, generating an electrical discharge in the gas. Energy is transferred to the gas, which then emits the energy in the form of light. The gas is chosen to have a lot of energy emitted in the UV region. Mercury was used in early bulbs but I suspect they have been substituting other gases as they try to phase out uses of mercury. The UV light hits the phosphor on the inside of the tube, which absorbs the energy and re-emits the energy at a lower (visible) wavelength. Many types of glass absorb UV light so little of it is emitted by the fluorescent bulb (but you do get some).
The discharge in the gas is electrical, and is run on AC at the normal line frequency (50-60 Hz). Since AC goes in both directions, the discharge is generated at twice that frequency (100-120 Hz). Newer fluorescent lamps use a higher frequency which alleviates some of the problems described below.
The light from the gas discharge occurs at a group of wavelengths specific to the type of gas used. The phosphor converts that to a more continuous spectrum, but the shape of the spectrum will depend on the phosphor used. Generally a mixture of phosphors is used to refine the shape of the output spectrum. Fluorescent lights are available in a number of different spectral distributions, for example “daylight”, “cool white”, and “warm white”, as well as some specialty distribution such as growing lamps, which match the spectrum needed for plant photosynthesis, generally heavy in the red and blue and light in the green (which is reflected by the plant leaves).
Since the gas discharge turns on and off driven by the line voltage, the UV light is intermittent. The phosphors emit light after the UV light turns off but the intensity of the emitted light will diminish exponentially with time until the voltage rises and the UV light turns on again. The decay rate of the phosphor depends on the particular phosphor used, and since phosphors are generally a mixture of materials, the spectrum will change in a complex way with time. Every different material has a different decay rate for the emitted light
I found a couple examples of fluorescent light spectra online, presented below. As noted above, these are not static spectra, but most likely averages over an integral number of power line cycles. The broad curves are the spectra due to the phosphors and the spikes are the spectra due to the gas discharge. There is clearly a wide variation in the spectra you will get from these light sources. Just to remind you, UV light has wavelengths shorter than around 400 nanometers and visible light is roughly between 400 and 700 nanometers. Above 700 nanometers is infrared.
Sources:
www.comsol.com/blogs/calculating-the-emission-spectra-from-common-light-sources/en.wikipedia.org/wiki/File:Spectrum_of_halophosphate_type_fluorescent_bulb_(f30t12_ww_rs).png
To see the time variation of the spectrum I took my camera and took several shots of a fluorescent lamp with the shutter set at 1/1000 second. My camera has a focal plane shutter so the actual exposure takes about 1/250 second, which is the time taken for the shutter to fully transit the frame. The image below is five such shots cropped to show just the fluorescent bulb and placed side by side. The travel of the shutter is along the length of the fluorescent bulb so what you see is the variation of the light coming from the bulb over that 1/250 second. The timing of the shots is random compared to the phase of the AC line so the shots will show the variation at different starting points. At the left of the illustration, the bulb is illuminated for the whole 1/250 second of the exposure. Just to the right of that, the gas discharge is on at the start of the exposure (bottom of the frame) and turns off just after the exposure starts so you can see the light from the phosphors start to decay. In the center the decay is further along and the light starts to look yellowish. Then there’s a wide yellow band in the center and the gas discharge starts up at the top of the frame. Last image (right side) shows the gas discharge off (bottom of the frame), then it turns on so the top of the frame is fully illuminated. The diffuse band between off and on is partly the time it takes for the discharge to get to full intensity and partly due to the width of the shutter opening. The shots are not sequential since they are at a random phase relative to the power line. I just arranged them to look sequential.
Since there is a variability of the effective color temperature of the illumination with fluorescent lighting, different shots will need different adjustments for white balance, particularly if the shutter speed is shorter than half the time between power line cycles. The effect will be lower for longer shutter speeds but unless the shutter speed is not an integral number times the time between power line cycles there will be some effect.
As mentioned above, some of the newer fluorescent systems use a higher frequency for the discharge so the phosphor decay will not be as important and the variability of the white balance between shots will be reduced.
LED light sourcesWhile LED lights have less of the spiky nature of fluorescent sources, they are not really like a black body source. They do have some structure, and the structure will depend on the blend of different LED sources in a lamp.
Source: electronics.stackexchange.com/questions/149683/do-standard-white-leds-produce-a-full-spectrum-of-light
The color of a LED depends on the materials used to construct the LED. Many LEDs are combinations of different color LED components, so the spectrum shown above is not representative of all LED light sources.