downing wrote:
Why do Hi ISO pictures lose saturation of color?
Is it a physical limitation of the sensor?
Does the reflectance of objects change with changes in Illumination level?
???
If it is the sensor what trade offs could be made to improve performance?
It has nothing to do with ISO, dynamic range or noise. It is simply the result of how the colors get mixed in the visible 8- or 16-bit image.
Take an image with a pure saturated red area. The color in the 8-bit image would be red=255, blue=0 and green=0. You can't make the red any more intense or brighter because it is at the upper limit. You can only make it darker by reducing the 255 value. As the value goes down, it initially looks pretty saturated but as it get darker (blacker) the redness declines until it is no longer clearly visible. It will have become blacker and when it reaches 0 you will see pure black.
Now try to increase the brightness. You can't add any more red. You can only add blue and green. This makes it brighter but the red saturation declines. Once the blue and green reach 255 you have white.
This happens if you start with any of the RGB colors:
Saturated Darker Lighter
Red 255,0,0 127,0,0 255,127,127
Green 0,255,0 0,127,0 127,255,127
Blue 0,0,255 0,0,127 127,127,255
If you use one of the complimentary CMY colors the numbers are a different but the logic is the same:
Saturated
Cyan 0,255,255
Magenta 255,0,255
Yellow 255,255,0
It gets a little more complicated with colors other than RGB or CMY.
The only time that high ISO gets involved is when it leads you to overexpose one or more of the primary RGB values in the raw file.